Colors

Hey, I really need some advice. I am using X5 and print on a Cannon wide format inkjet printer. I use RGB colors, but I'm having a problem printing on adhesive vinyl. I used R255 G0 B0 that I've used on other medias, but it came out a little orange. I really need a good red to use or help with my settings. Any help anyone can give will be greatly appreciated!!

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